Not far behind on the teperature resistance of G10 and cheaper would be polycarbonate sheet Polycarbonate SheetFrom what you have described I would suggest
G10 Sheet
Comes in different thicknesses and panel sizes.
10 mm acrylicThat's all quite vague.
Do you need to insulate thousands of volts? How much leakage can you tolerate?
How heat resistant? 100degC or 1000?
What mechanical properties are required?
Does it have to look pretty?
Glass, ceramics, fibre cement, plasterboard, mica,
Will go on fire.....10 mm acrylic