Lithium battery fire risks

Here's a good example (below) of reporting fire risks on boats caused by 'lithium'. 1. A supertanker on fire, 2. A Russian submarine where people died of toxic gas emitted by the batteries. 3. Many super-yacht fires.

1. Seems to be caused by short circuiting fire. That is, not arising from LFP chemistry
2. A lithium technology "like that used in mobile phones". In other words, not LFP
3. The single example cited was caused by a surf-board battery on charge, so again, not LFP.

Short circuits - either from failure to construct a robustly secured and insulate battery pack or having a main fuse with insufficient amperage interrupt capacity [more common fuses used on boats can allow arcing or the metal components can fuse under the heat] are a greater risk with LFP than lead acid because of the much higher energy density and low internal resistance allowing masses of current to flow into a dead short. But such fires are then caused by poor installation and fusing practices rather than the chemistry itself.

Battery fire safety marine : the rising risk of Lithium batteries - LithiumSafe

And this, from a linked article on lithium fires on super-yachts, points clearly to the many items carried on by passengers as the cause with battery-powered surf boards a major culprit. Charging of these items is the period of risk.

"As owners and guests have begun demanding more technology on board, an increasingly large number of third-party elements are being added to the vessel’s cargo, many of which rely on Lithium-ion batteries. These batteries are typically used in technologies that require charging. They are inexpensive, lightweight, powerful and, unfortunately, extremely combustible. For this reason, is it advisable that crew pay special attention to the risks associate with Lithium-ion batteries and how these differ from product to product."
 
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In summary ...

1. A well designed and installed LiFePO4 (LFP) battery system on a boat does not carry an undue risk of fire and risks that arise from poor installation are not related to unstable chemistry.
2. Other lithium ion batteries which trade smaller size and higher energy density for inherent safety do carry a small risk of thermal runaway and hard-to-quench fire.
3. Such risks are manifest when charging.
4. These batteries should not be left unattended charging on a boat and should never by covered - especially with flammable material - when charging.
5. Fire extinguishers are emerging specific to small lithium ion batteries as well as safe charging containers that can be picked up and thrown overboard.
6. Don't buy an electric surfboard!

Summary of the summary ...
Worry about the right things. It is irrational to say that you would never have lithium batteries on your boat because of fire-risk while carrying a mobile phone.
 
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I wonder how many pages will fill with alternating messages about how dangerous X is that isn't a boat battery system and posts explaining that while dangerous X is not generally found on boats ?

I'll keep this going by highlighting the high lithium content of dried nuts, which burn pretty readily once ignited.
 
For those of you that don't appreciate the difference betweel Lithium and LiFePO4 (LFP) well it is simple really. It is the same as the difference between Dioxin and Meta Dioxin

 
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