My anodes have lots of metal left on them but are partially covered in a white deposit. I read a recent article that said anodes should never be cleaned. Can anyone explain why?
I always wire brush mine as well, as I figured that the white deposit would inhibit the small electrolytic currents - but I could be (as usual) quite wrong!!!
I understood the white deposit is the degraded zinc and removal will make the anode more effective, but it should then erode quicker.
I've always also used a wire brush as anodes costs less than a prop - but guess we should all assume the recommneded sized anode with the deposit on should still be operating to its specification.
Or should we?
If any one has the scentific answer - maybe a Mr Anode Maker himself - love to clear this one up.
Cheers
JOHN
The white deposit is oxidised zinc, and once it is coating the surface of the anode, it will effectively provide an insulation layer. So, the deposits should be removed, or the anode will not be functioning as well as a non-oxidised one. Sandpaper or scraping work well.
If the anode is significantly reduced in size and coated, then better to replace.
With my non scientific hat on cos sacrificial protection seems to be black magic with some science added to give it respectability.
I would say that replacing anodes is a bit like reefing,if your thinking about it;do it!
Better in both cases to do too much than too little.
With scientific hat on I would say that if you have lots of white deposits on an anode it may indicate that the zinc is acting as zinc and not as an anode,in which case you may want to check your bonding to whatever the anode is meant to be protecting.
I read somewhere a while ago that it's the wire-brushing that's the problem, not the cleaning itself. Apparently the surface of the anode is changed chemically in some way by the action of the brush.
I'm only reporting what I read - no I don't understand it either, but have ever since then used emery to clean anodes, which have then continued to work.
Perhaps the anti-wire-brusher will raise his/her head?
Some purist may say that using metal brushes may contaminate the anode and affect it's composition, thereby reducing it's effectiveness, so only use stainless steel or non metallic brushes, but in the real world, I really wouldn't worry about it. Such purity is only necessary when anodes are being used in plating or other similar processes, not when on boats.
Use sandpaper if you feel happier, but it's really not going to have a significant effect.
I can think of other reasons for not using metallic brushes though, not least of which is the chance of damaging the coating on aluminium (eg on sterndrives) close to the anode, or the chance of bits of ferrous metal getting embedded in glassfibre and then rusting (been there, done that, when I hacksawed off the shackle off an anchor and ended up with speckles of rust all over the gelcoat in the area!)
Brendan,
Perhaps they could be cleaned with oxalic acid, mixed with wallpaper paste of course. It seems to be the magic 'clean all' chemical of the moment. What do you think? /forums/images/graemlins/wink.gif /forums/images/graemlins/wink.gif
The problem with wire brushing could be that bits of wire left imbedded in the anode will accelerate the the rate of loss of zinc.
Never mind Oxalic acid, a good dose of concentrated phosphoric acid will have the anodes clean in no time! <gg>
I still don't think in the real world that bits of wire embedded in the zinc is likely. On the odd chance you do get a bristle embedded, then you can just pull it out. The tiny amount of metal lost through abrasion isn't going to hang around long.
As I said in an early post in the thread, if anyone thinks it's worth worrying about, just use stainless brush, or sandpaper.
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Phosphoric won't be a good choice because zinc phosphate is insoluble.
I thought you might have pulled me up over the insolubility of zinc oxalate!
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Eek, thought we were joking! Too late at night to think about insolubility of anything
The reason most anode people recommend stainless steel brushes is that they are tough, and so very unlikely to leave bits behind, rather than soft wire metal brushes