Copper corrodes when it comes in contact with sea water it goes green / black .. Marine grade wiring is tinned copper so it does not corrode .. Had some light flex that was fitted on the old boat .. after about a year it was corroded about 300 mm from the end .. Also explains why its expensive .. The last thing you want is failed or failing wiring ..
As finn sailor says, corrosion is a major issue. I have had terrible trouble over the years and curse out loud when I find the boatbuilder or PO has wired in untinned. If you mean non-stranded cable then there is another problem...solid cores of copper tend to work-harden with vibration. Fine for a house but for many applications in a boat totally unacceptable.
beg to differ, most of the extra wiring we have put into a halcyon clipper 27 (ie there was not much to start with) has been single core copper about that dia. no corrosion problems (single core). sure once it is bent to fit the shape of the boat, you shouldn't bend it again, but its all 30 years old now with no problems at all unlike multi strand.
oh and our engine is bolted directly to the hull for maximum vibration, so if it was going to work harden i'm sure it would have done it by now. it is all clipped on securely, maybe this helped.
we have had problems with any multistrand wire, doubt they were tinned. the corrosion is only on the surface of the metal, hence why we favour the single strand. and all because it was left over from a house rewire...
Depends how much current you want to push down it. Yes, tinned copper wire is preferable for corrosion resistance, but if you want it to carry amps to your windlass, you may find tinned wire hard to come by and 1.5mm2 far too small.