Are you sure that it's an RCD you are after? Could you be getting it confused with an MCB (minature circuit breaker)? However I don't know if these are available in 12V
If it's really MCBs you're after, as suggested by JAMESMAR, they are readily available. All usual types are not voltage dependant for operation (though they will have max voltage and current ratings which will differ for AC and DC). Main choices are between thermal and magnetic types (or combination of both).
I can't see any theoretical reason why one couldn't design a DC Residual Current Device (RCD). It would have to work quite differently from a 'normal' RCD though, requiring shunts in both the positive and negative feeds (with associated voltage drops which could be large given the sensitivity you would presumably require). No such commercial device exists to the best of my knowledge.
Probably easier ways to achieve whatever it is you are thinking of /forums/images/graemlins/smile.gif
Interested to know why not. Opposing magnetic fields which cancel when out and back currents are equal. Or is it the reaction circuit breaker that causes non operation on DC?
Agree with 'Why?' ... can only think Chouchou is concerned with electrolysis issues.
Considered the Hall Effect (or similar) route, but concluded unlikely to achieve the required sensitivity (surely way under 30mA if electrolysis is the issue?) when also considering the likely current draw device must accept.
Have been out of the area for some years, so will be interested if there are now approaches that would now work in practice. (PM if you think getting too technical for general interest).